Tiwari Group

43

Iodobenzene Catalyzed Synthesis of Fully Functionalized NH-Pyrazoles and Isoxazoles from α,β- Unsaturated Hydrazones and Oximes via 1,2-Aryl Shift

Vikram Singh, Deepak Kumar, Balkrishna Mishra and Bhoopendra Tiwari*

Org. Lett. 2024, 26, 1, 385–389

42

Construction of Highly Functionalized C4-Oxyacylated and Aminated Pyrazolines

Vikram Singh, Balkrishna Mishra, Deepak Kumar and Bhoopendra Tiwari*

Org. Lett. 2023, 2539, 7089-7094

41

Cassia fistula galactomannan stabilized copper nanocatalyst as an efficient, recyclable heterogeneous catalyst for the fast clickable [3+2] Huisgen cycloadditions in water

J. Pandey, B. SinghH. KhanamBhoopendra TiwariT. AzazR. Singh

Int. J. Bio. Macromol. 2023, 255, 128098

40

N-Heterocyclic Carbene-Catalyzed Enantioselective [3 + 2] Annulation of Enals with Vinyl Ketones

Tazeen Azaz, Hemlata Mourya, Vikram Singh, Bali Ram and Bhoopendra Tiwari*

J. Org. Chem. 2023, 88, 1219-1226

39

Reductive Alkenylation of Ketimines via Hydride Transfer from Aldehydes

Tazeen Azaz, Hemlata Mourya, Vikram Singh, Bali Ram and Bhoopendra Tiwari*

J. Org. Chem. 2023, 88, 632-639

38

Metal-free synthesis of nitriles from aldehydes using N-Boc-O-tosylhydroxylamine as a nitrogen source

Puneet Kumar, Vikram Singh, Jawahar Lal Jat* and Bhoopendra Tiwari*

New J. Chem. 2023, 47, 535-538

37

Novel Functionalized Spiro [Indoline-3,5′-pyrroline]-2,2′-dione Derivatives: Synthesis, Characterization, Drug-Likeness, ADME, and Anticancer Potential

M. Asif, S. S. Alvi, T. Azaz, A. R. Khan, Bhoopendra Tiwari, B. B. Hafeez and M. Nasibullah

Int. J. Mol. Sci 2023, 24, 7336

36

Propagative isatin in organic synthesis of spirooxindoles through catalysis (Review)

Mohd Asif, Tazeen Azaz, Bhoopendra Tiwari, Malik Nasibullah

Tetrahedron 2023, 134, 133308

35

Carbene Catalyzed Asymmetric Synthesis of Selenylated δ-Lactones via [4+2] Annulation of Selenyl Vinyl Ketones and Enals

Ram Subhawan Verma, Ranadeep Talukdar, Tazeen Azaz and Bhoopendra Tiwari* 

Adv. Synth. Catal. 2022, 364, 4031-4035

34

Metal-free synthesis of secondary amides using N-Boc-O-tosylhydroxylamine as nitrogen source via Beckmann rearrangement

Jawahar Lal Jat,* Puneet Kumar, Soumya Verma, Dinesh Chandra, Vikram Singh and Bhoopendra Tiwari*

  New. J. Chem. 2022, 46, 14782-14785

33

Metal and Additive-Free Intermolecular Aziridination of Olefins Using N-Boc-O-Tosylhydroxylamine

Jawahar Lal Jat,* Dinesh Chandra, Puneet Kumar, Vikram Singh and Bhoopendra Tiwari* 

Synthesis, 2022, 54, 4513-4520

32

Direct N-Me Aziridination of Enones

Jawahar Lal Jat,* Ajay K. Yadav, Chandra Bhan Pandey, Dinesh Chandra and Bhoopendra Tiwari* 

J. Org. Chem. 202287, 3751-3757

31

Catalytic Enantioselective Syn-Hydroxy-Oxyacylation of Electron Deficient Alkenes

Chandra Bhan Pandey, Vikram Singh, Susanta Ghanta and Bhoopendra Tiwari* 

ChemRxiv 2021

30

A General Method for α-Oxyacylation of Vinyl Ketones Using Koser’s Reagent

Chandra Bhan Pandey, Bal Krishna Mishra, Tazeen Azaz, Hemlata Mourya, Bali Ram, and Bhoopendra Tiwari*

J. Org. Chem. 202186, 17318-17328

29

Carbene Catalyzed Access to 3,6-Disubstituted α-Pyrones via Michael Addition/Lactonization/Elimination Cascade

Anil Kumar Khatana, Vikram Singh, Manoj Kumar Gupta and Bhoopendra Tiwari*

Adv. Synth. Catal. 2021363, 4862-4865

28

Stitching Triazoles to Arenes via a Transition Metal-Free Aryne Diels-Alder/1,3-Prototropic Shift/Dehydrobromination Cascade

Ranadeep Talukdar, Vikram Singh, Hemlata Mourya, Malik Nassibullah and Bhoopendra Tiwari*

J. Org. Chem. 202186, 12277-12284

27

Fe(II)-Catalyzed Synthesis of Unactivated Aziridines (N-H/N-Me) from Olefins Using O-Arylsulfonyl Hydroxylamines

Dinesh Chandra, Ajay K. Yadav, Vikram Singh, Bhoopendra Tiwari* and Jawahar L. Jat*

Chemistry Select 202106, 10524-10526

26

Access to enantioenriched 4-phosphorylated δ-lactones from β-phosphorylenones and enals via carbene organocatalysis

Ram Subhawan Verma, Anil K. Khatana, Monika Mishra, Shailesh Kumar and Bhoopendra Tiwari*

Chem. Commun. 202056, 7155-7158

25

Stereoselective Oxidative Rearrangement of Di-Substituted Unactivated Alkenes Using Hypervalent Iodine(III) Reagent

Chandra Bhan Pandey, Tazeen Azaz, Ram S. Verma, Monika Mishra, Jawahar L. Jat and Bhoopendra Tiwari*

J. Org. Chem. 202085, 10175-10181

24

Global Access to 3/4-Phosphorylated Heterocycles via a Carbene-Catalyzed Stetter Reaction of Vinylphosphonates and Aldehydes

Ram Subhawan Verma, Monika Mishra, Chandra Bhan Pandey and Bhoopendra Tiwari*

J. Org. Chem. 202085, 8166-8175

23

Direct Synthesis of Secondary Amides from Ketones through Beckmann Rearrangement using O-(Mesitylsulfonyl)Hydroxylamine

Dinesh Chandra, Soumya Verma, Chandra Bhan Pandey, Ajay K. Yadav, Puneet Kumar, Bhoopendra Tiwari* and Jawahar L. Jat*

Tet. Lett.  2020, 61, 151822

22

Zinc(II)-Catalyzed Synthesis of Secondary Amides from Ketones via Beckmann Rearrangement Using Hydroxylamine-O-sulfonic Acid in Aqueous Media

Soumya Verma, Puneet Kumar, Anil K. Khatana, Dinesh Chandra, Ajay K. Yadav, Bhoopendra Tiwari* and Jawahar L. Jat*

Synthesis202085, 8166-8175 [ Invited Contribution]

21

Carbene/Base-Mediated Redox Alkenylation of Isatins using β-Substituted Organoselenones and Aldehydes

Atanu Bhaumik, Tazeen Azaz, Vikram Singh, Anil K. Khatana and Bhoopendra Tiwari*

J. Org. Chem. 201984, 14898-14903

20

Construction of Phenanthrenes and Chrysenes from β-Bromovinylarenes via Aryne Diels–Alder Reaction/Aromatization

Vikram Singh, Ram Subhawan Verma, Anil K. Khatana and Bhoopendra Tiwari*

J. Org. Chem. 201984, 14161-14167

19

Direct N-H/N-Me Aziridination of Unactivated Olefins Using O-(Sulfonyl)hydroxylamines as Aminating Agents

Shekh Sabir, Chandra Bhan Pandey, Ajay K. Yadav, Bhoopendra Tiwari* and Jawahar L. Jat*

J. Org. Chem.  2018, 83, 12255-12260

18

A Highly Efficient NHC-Catalyzed Aerobic Oxidation of Aldehydes to Carboxylic Acids

Anil K. Khatana, Vikram Singh, Manoj Kumar Gupta and Bhoopendra Tiwari*

Synthesis 201850, 4290-4294 [ Invited Contribution]

17

Carbene-Catalyzed Tandem [1,2]-Phospha-Brook/[1,4]-Phosphate Rearrangement: Access to α-Ketophosphates via Controlled Cross-Acyloin Condensation

Ram Subhawan Verma, Chandra Bhan Pandey, Shailesh Kumar and Bhoopendra Tiwari*

J. Org. Chem. 201883, 9478-9483

16

Direct Construction of 2,3-Dihydroxy-2,3-diaryltetrahydrofurans via N-Heterocyclic Carbene/Base-Mediated Domino Reactions of Aromatic Aldehydes and Vinyl Selenone

Atanu Bhaumik, Ram Subhawan Verma and Bhoopendra Tiwari*

Org. Lett. 201719, 444–447

15

Catalytic Activation of Carbohydrates as Formaldehyde Equivalents for Stetter Reaction with Enones

J. Zhang, C. Xing, B. Tiwari, Y. R. Chi

J. Am. Chem. Soc2013135, 8113–8116 [The Most read article of June 2013]

14

Asymmetric Access to the Smallest Enolate Intermediate via Organocatalytic Activation of Acetic Ester

S. Chen, L. Hao, Y. Zhang, B. Tiwari, Y. R. Chi

Org. Lett201315, 5822–5825

13

Organocatalytic Activation of α-Alkyl Carboxylic Esters as Enolate Precursors to React with α,β-Unsaturated Imines

L. Hao, S. Chen, J. Xu, B. Tiwari, Z. Fu, Y. R. Chi

Org. Lett201315, 4956-4959

12

Controlled β-Protonation and [4+2] Cycloaddition of Enals and Chalconesvia N-Heterocyclic Carbene/Acid Catalysis: Toward Substrate Independent Reaction Control

Z. Fu, H. Sun, S. Chen, B. Tiwari, G. Li, Y. R. Chi

ChemCommun201349, 261–263 [Highlighted in Synfacts]

11

Direct α-Functionalization of Simple Aldehydes via Oxidative N-Heterocyclic Carbene Catalysis

J. Mo, R. Yang, X. Chen, B. Tiwari, Y. R. Chi

Org. Lett201315, 50–53 [Among top 5 most read articles of the month]

10

Enantioselective Oxidative Cross‐Dehydrogenative Coupling of Tertiary Amines to Aldehydes

J. Zhang, B. Tiwari, C. Xing, X. Chen, Y. R. Chi

Angew. Chem. Int. Ed201251, 3649–3652

9

Facile Access to Chiral Ketones through Metal-free Oxidative C-C Bond Cleavage of Aldehydes by O2

B. Tiwari, J. Zhang, Y. R. Chi

Angew. Chem. Int. Ed201251, 1911–1914

8

Highly Enantioselective Addition of Enals to Isatin-Derived Ketimines Catalyzed by N-Heterocyclic Carbenes: Synthesis of Spirocyclic γ-Lactams

H. Lv, B. Tiwari, J. Mo, X. Chong, Y. R. Chi

Org. Lett201214, 5412–5415 [Highlighted in Synfacts]

7

Enantioselective Intramolecular Formal [2+4] Annulation of Acrylates and α,β– Unsaturated Imines Catalyzed by Amino Acid-Derived Phosphines

Z. Jin, R. Yang, Y. Du, B. Tiwari, R. Ganguly, Y. R. Chi

Org. Lett201214, 3226–3229

6

Access to Spirocyclic Oxindoles via N-Heterocyclic Carbene-Catalyzed Reactions of Enals and Oxindoles-Derived α,β-Unsaturated Imines

K. Jiang, B. Tiwari, Y. R. Chi

Org. Lett. 201214, 2382–2385

5

Addition of Indoles to Oxyallyl Cations for Facile Access to α-Indole Carbonyl Compounds

Q. Tang, X. Chen, B. Tiwari, Y. R. Chi

Org. Lett201214, 1922–1925

4

Synthesis of the C10-C24 fragment of (+)-Cannabisativine

3

Chiral pyrrolidine-triazole conjugate catalyst for asymmetric Michael and Aldol reactions

S. Chandrasekhar, B. Tiwari, B. B. Parida, C. R. Reddy

Tetrahedron: Asymmetry 200819, 495–499

2

Asymmetric synthesis of a protected dihydroxy piperazic acid derivative

S. Chandrasekhar, G. Parimala, B. Tiwari, C. Narsihmulu, G. D. Sarma

Synthesis 200711, 1677–1682

1

Concise synthesis of truncated pachastrissamine (jaspine B) and its enantiomer

S. Chandrasekhar, B. Tiwari, S. J. Prakash

ARKIVOC 2006, (xi), 155–159

Patents

4

A process for the synthesis of α,β-unsaturated amides

Jawahar L. Jat, Soumya Verma, Vikram Singh and Bhoopendra Tiwari

Indian patent (2023); Application No. 202311036104

3

Method for Metal-Free Synthesis of Secondary Amides using N-Boc-O-Tosylhydroxylamine as Nitrogen Source via Beckmann Rearrangement

Jawahar L. Jat, Puneet Kumar, Soumya Verma, Dinesh Chandra, Vikram Singh and Bhoopendra Tiwari

Indian patent (2023); Application No. 202211077495

2

Novel Method for Metal-Free Synthesis of Nitriles from Aldehydes using N-Boc-O-Tosylhydroxylamine as Nitrogen Source 

Puneet Kumar, Vikram Singh, Jwahar L. Jat and Bhoopendra Tiwari

 Indian patent (2023); Application No. 202211077473

1

Methods of Preparing Chiral Ketones from Aldehydes

Bhoopendra Tiwari and Yonggui R. Chi

Indian patent (2013), WO 2013095301 A1 20130627